here is thepainting i did couple days ago.
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The sketch
the flats ( midtones ) i always put warmer tone on areas where there are more blood presure such as the nose, ears and so.
Applying the Key light is often a struggle for me but enventualy it end up turing pretty well.
This is almost the final step, i just
liquify here and there add some other effect like, make the key light a bit gloomy effects.
the reference i used, I didn't capture the mood though.